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  • Flow-Field Design

    As was noted in Section 10.4, the fuel and oxidant must be directed over the surface of anode and cathode in the fuel-cell stack. Most often this is done with rectangular channels. The set of channels make up the flow field. Drawing on what we have learned in the previous sections, we now have a…

  • Utilization of Oxidant and Fuel

    For both the fuel and oxidant streams, utilization is an important design factor. The utilization of fuel plays a key role in the fuel efficiency, and the utilization of the oxidant, typically air, affects the mechanical efficiency of the system and polarization losses in the cell. We’ll first consider the oxidant by examining the cathode of a…

  •  Basic Construction and Components

    Let’s now take a more detailed look at the components of a bipolar fuel-cell stack as illustrated in Figure 10.4. Multiple layers are assembled together to form a cell, and these layers are arranged like a deck of cards to form the stack. Starting from the center of the cell in Figure 10.4 and working out, the electrolyte…

  • Cell Stack Configurations

    Potentials of individual cells are about 1 V. Most applications require at least a few volts, but often hundreds of volts are desired. Single cells can be fabricated and then connected in series to increase the voltage, just as is done in batteries. The first approach, which is used commonly in batteries, is referred to as…

  • Basic Stack Design Concepts

    In this section, we consider the initial or basic design of the fuel-cell stack. The fuel-cell stack is part of the fuel-cell system, which itself is part of a larger system. Therefore, some of the important design specifications and constraints for the fuel-cell stack are derived from the high-level requirements of the larger system. For…

  • Introduction and Overview of Systems Analysis

    In contrast to the battery, a fuel cell is typically a steady-state device. As such, the fuel and oxidant are supplied continuously. In the previous chapter, we focused on the electrochemistry of the fuel cell. Now we will examine the entire fuel-cell system. Many cells are combined to form a cell stack assembly (CSA), which…

  • Solid Oxide Fuel Cells

    A second major type of fuel cell is the SOFC. Here the electrolyte is a ceramic material that conducts oxygen ions. The electrode reactions for a SOFC were provided in Table 9.2. Note that in contrast to the PEMFC, although the overall reaction is the same, water is produced at the anode rather than the cathode. Additionally,…

  • Proton-Exchange Membrane (PEM) Fuel Cells

    The electrolyte in PEM fuel cells is a solid polymer material with covalently bonded sulfonic acid groups. These materials are similar to ion-exchange resins. A cation is associated with each negatively charged sulfonic acid group. For fuel-cell applications, the cations are protons. In other applications, see Chapter 14 and the chlor-alkali process, sodium ions are present rather…

  • Electrode Structure

    Electrode structures were introduced in Chapter 5. One of the distinguishing features of a fuel-cell electrode is that three phases are present. First, there is a solid phase that is electronically conductive to supply or remove electrons. Second, an electrolyte phase that conducts ions is needed. The electrolyte may be solid or liquid. So far, this…

  • Current–Voltage Characteristics and Polarizations

    A key objective in this chapter is to gain a detailed understanding of what is known as the polarization curve. This curve represents the steady-state relationship between the potential of the cell, Vcell, and its current density, i. It is typically measured experimentally. During this measurement, the temperature and pressure are held constant, and the flow of reactants…