Practice Problems

P11.1. Ninov et al. (J. Chem. Eng. Data, 40:199, 1995) have shown that the system diethylamine(1) + chloroform(2) forms an azeotrope at 1 bar, 341.55 K and x1 = 0.4475. Is this a maximum boiling or minimum boiling azeotrope? Determine the bubble temperature and vapor composition at x1 = 0.80 and 1 bar. (ANS. 331 K, 0.97)

P11.2. Derive the expression for the activity coefficient of the Redlich-Kister expansion.


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