Flotation separation

Flotation is the most widely used method for the concentration of fine-grained minerals. It takes advantage of the different physicochemical surface properties of minerals—in particular, their wettability, which can be a natural property or one artificially changed by chemical reagents. By altering the hydrophobic (water-repelling) or hydrophilic (water-attracting) conditions of their surfaces, mineral particles suspended in water can be induced to adhere to air bubbles passing through a flotation cell or to remain in the pulp. The air bubbles pass to the upper surface of the pulp and form a froth, which, together with the attached hydrophobic minerals, can be removed. The tailings, containing the hydrophilic minerals, can be removed from the bottom of the cell.

Flotation makes possible the processing of complex intergrown ores containing copper, lead, zinc, and pyrite into separate concentrates and tailings—an impossible task with gravity, magnetic, or electric separation methods. In the past, these metals were recoverable only with expensive metallurgical processes.

Magnetic separation

Magnetic separation is based on the differing degrees of attraction exerted on various minerals by magnetic fields. Success requires that the feed particles fall within a special size spectrum (0.1 to 1 millimetre). With good results, strongly magnetic minerals such as magnetite, franklinite, and pyrrhotite can be removed from gangue minerals by low-intensity magnetic separators. High-intensity devices can separate oxide iron ores such as limonite and siderite as well as iron-bearing manganese, titanium, and tungsten ores and iron-bearing silicates.

Electrostatic separation

The electrostatic method separates particles of different electrical charges and, when possible, of different sizes. When particles of different polarity are brought into an electrical field, they follow different motion trajectories and can be caught separately. Electrostatic separation is used in all plants that process heavy mineral sands bearing zircon, rutile, and monazite. In addition, the cleaning of special iron ore and cassiterite concentrates as well as the separation of cassiterite-scheelite ores are conducted by electrostatic methods.